Sponge-like biodegradable polypyrrole-modified biopolymers for selective adsorption of basic red 46 and crystal violet dyes from single and binary component systems

Abstract

Recently, several researchers have been trying to reduce the ecological effects of water pollution by considering the use of biodegradable materials that prevent the generation of secondary pollution in our environment and enable water reuse. Here, new biodegradable hydrogels based on alginate (Alg), gelatin (Gel) and polypyrrole (PPy) were successfully implemented to remove two known highly toxic cationic dyes from wastewater. The design process was performed in two steps: in-situ polymerization of polypyrrole within the Alg/Gel mixture, followed by hydrogel formation. Biocomposites showed promising efficacy for the removal of both basic red 46 (BR46) and crystal violet (CV) dyes from real and demineralized water samples. However, Alg-Gel-PPy hydrogel showed better selectivity for BR46 than for CV as compared to the pristine Alg-Gel hydrogel. Adsorption of both pollutants on biocomposite hydrogel beads followed the Langmuir isotherm and pseudo-second order kinetic models. Besides, the highest adsorption capacities (125 mg g−1 for BR46 and 88.5 mg g−1 for CV) were obtained for the Alg-Gel-PPy hydrogel, compared with those determined for PPy-free hydrogel (103.09 mg g−1 for BR46 and 86.96 mg g−1 for CV) and remained at a satisfactory level for five adsorption-desorption cycles. Finally, the obtained hydrogels showed excellent biodegradability by natural soil microorganisms, with 91 % decomposition.