Abstract
Ferrous chloride complexes [FeIILxCl] commonly attain a high-spin state independently of the supporting ligand(s) and temperature. Herein, we present the first report of a complete spin crossover with T1/2 = 80 K in [FeII(Py5OH)Cl]+ (Py5OH = pyridine-2,6-diylbis[di(pyridin-2-yl)methanol]). Both spin forms of the complex are analyzed by X-ray spectroscopy and DFT calculations.
Highlights
ISSN 1359-7345 COMMUNICATION Shyh-Chyang Luo, Atsushi Takahara et al Synthesis of a conductive polymer thin film having a choline phosphate side group and its bioadhesive properties
Spin transition in a ferrous chloride complex supported by a pentapyridine ligand†
We present the first report of a complete spin crossover with T1/2 = 80 K in [FeII(Py5OH)Cl]+ (Py5OH = pyridine-2,6-diylbis[di(pyridin-2-yl)methanol])
Summary
ISSN 1359-7345 COMMUNICATION Shyh-Chyang Luo, Atsushi Takahara et al Synthesis of a conductive polymer thin film having a choline phosphate side group and its bioadhesive properties. Spin transition in a ferrous chloride complex supported by a pentapyridine ligand†
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