Abstract
Abstract In the photochemical electron transfer reactions of t-alkylamine and p-benzoquinone in liquid, emissively spin-polarized transient anion radicals from p-benzoquinone(PBQ) and 2,5- or 2,6-di-t-butyl-p-quinone(25Q or 26Q) are exclusively produced by photo-excitation of benzophenone(BP) in a magnetic field. Transient radicals of quinones with different unpaired spin distribution are obtained at the onset of photolysis.
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