Abstract

The range of observables in zero kinetic energy (ZEKE) electron spectroscopy of molecules, previously restricted to the total electron intensity, was extended by measuring the integral spin polarization of ZEKE electrons at the HBr Ω+=3/2 thresholds after single-photon excitation with narrow-band circularly polarized light. A comparison with calculated values from multichannel quantum defect theory underlines the importance of autoionization for the decay dynamics.

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