Abstract
The absorption intensity of the3B1 ←1A1 transition of nitrite salts of the non-transition metals is markedly dependent on the metal counterion and is causative of the yellow-orange colors of the heavier-metal salts. It is assumed that spin-orbit coupling is responsible for this phenomenon; this assumption is investigated here using semi-empirical one-electron calculations and is validated. The subjects of covalent bonding in metal salts, charge transfer transitions in such systems and the Sj ← S0 electronic spectroscopy of nitrite salts are also investigated.
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