Abstract
AbstractThe spin‐Hamiltonian parameters (g factors g‖, g⊥ and hyperfine structure constants 161A‖, 161A⊥, 163A‖, 163A⊥) for 161Dy3+ and 161Dy3+ isotopes in the trigonal 12‐fold coordinated La3+ site of La2Mg3(NO3)12·24H2O crystal are calculated from a diagonalization (of energy matrix) method. In the method, the Zeeman and hyperfine interaction terms are added to the conventional Hamiltonian used in the studies of crystal‐field energy levels, and a 66×66 energy matrix concerning the ground multiplet 6H15/2 and the first to fifth excited multiplets 6H13/2, 6H11/2, 6H9/2, 6H7/2 and 6H5/2 are applied. The calculated results are discussed. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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