Spherical and acicular representation of hydrates in a micromechanical model for cement paste: prediction of early-age elasticity and strength

Abstract

Early-age stiffness and strength evolution of cement paste is studied in the framework of continuum micromechanics. Based on the self-consistent scheme, elastic and strength properties are upscaled from the scale of several micrometers up to the scale of several hundreds or thousands of micrometers. Four material phases are considered: clinker, hydration products, water and air. We assign a spherical geometry to clinker grains and pores, while we investigate both spherical and acicular (needle-type) shapes as geometrical representation of the micrometer-sized hydration products. As regards macroscopic poromechanical boundary conditions, two extreme cases are considered: drained conditions and sealed conditions, respectively. These choices allow for studying the influence of (i) the morphological representation of hydrates, and of (ii) the bulk stiffness of water, on the micromechanical prediction of early-age behavior of cement paste, including setting and the hydration-dependent evolutions of both elastic stiffness and uniaxial compressive strength. The newly proposed strength model is based on a von Mises-type elastic limit criterion for individual hydrates. Corresponding deviatoric stress peaks within hydrates are estimated through quadratic stress averages. In this way, the micromechanical strength criterion is formulated in terms of macroscopic loading (stresses or strains, respectively). Model-predicted elasticity and strength evolutions are compared with data from experimental testing of cement pastes with water–cement ratios ranging from 0.35 to 0.60. Satisfactory agreement between model predictions and experiments allows for two conclusions: the morphology of hydrates significantly influences micromechanics-based elastic stiffness estimates of cement paste particularly at very early ages, whereas elastic properties of mature cement paste can be estimated reliably on the basis of both spherical or acicular shaped hydrates. The development of a reliable strength model, however, requires consideration of hydrates as non-spherical particles, no matter what age of cement paste is considered.