Abstract
A naphthalenediimide-based macrocycle with adamantane parts was synthesized from naphthalenetetracarboxylic dianhydride and 1,3-adamantanedimethanamine. The addition of methanol to a chloroform solution of the macrocycle led to formation of spherical species and their fused network aggregates, which were transformed into crystals. X-ray analysis showed a crescent-shaped molecular structure. In the presence of perylene, charge-transfer co-crystals of sandwich-type complexes were generated via self-assembly of nanostructures.
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