Abstract
The infra-red spectra of the acetamidinium ion [H 3C−C(NH 2) 2] + both in the chloride and in salts with complex anions of type MeCl 6 − as well as the spectrum of the deuterated ion [H 3C−C(ND 2) 2] + are assigned in terms of normal vibrations assuming a C 2 v -model. The interpretation of the spectra proves the structure assumed. Comparing the spectrum of the acetamidinium ion with those of its deuterated analogue and of isoelectronic ions leads to the conclusion that the assignment proposed by Davies and Parsons [3] is to be improved. The advantage of using complex salts in i.r.-spectroscopic studies of organic cations [4] is emphasized.
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