Abstract
By means of a new vibration formula of BRODERSEN, taking account of observed vibrational perturbations, the dissociation limit of the 3IIg states of C2 has been determined. In order to do this, some further SWAN bands (A3IIg—X′3IIu) and five high pressure bands (v′=6) have been analyzed. The extrapolations of vibrational levels of the A3IIg and B3IIg states lead to dissociation energies D0 (C2) = 6,07 eV and 6,09 eV, respectively, in good agreement with values obtained by other methods.
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