Abstract

Speed of sound measurements were made in methanol, ethanol, propan-1-ol, and butan-1-ol in the temperature range from (253.15 to 353.15)K at pressures up to 30MPa by use of a pulse-echo method with a double path type sensor. The expanded overall uncertainty (k=2) in speed of sound measurements are estimated to be 0.026% for methanol, 0.03% for ethanol, 0.013% for propan-1-ol and 0.01% for butan-1-ol. A double polynomial equation for the speed of sound with inputs of temperature and pressure has been fitted from the experimental results. These were compared with available literature sources and fundamental equations of state, showing good agreement among them to comparable alcohol purities and experimental uncertainties.

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