Abstract
PurposeThis paper aims to gain a greater insight into the molecular level changes occurring in lac‐epoxy blends, at elevated temperatures for different intervals of time. It is also to determine the changes in key physico‐chemical parameters of these blends, before and after applying thermal stress on these blends.Design/methodology/approachFilms of lac‐epoxy blends, applied on tin panels, were baked at 200°C for different time intervals. The baked films were examined by specular reflectance spectroscopy, as these were otherwise difficult to examine through conventional IR techniques, using KBr pellet method. The results obtained were compared and reported. The blends were also tested for different physico‐chemical parameters like scratch hardness, flexibility, adhesion, acid resistance, etc.FindingsOn baking the blends of lac‐epoxy resin at 200°C for different time intervals, the strained three membered epoxy ring apparently break open, releasing some free hydroxyl groups, which react with carboxylic groups in lac resin to form ester linkages, resulting in condensation. In terms of different physico‐chemical parameters, blends of 70 per cent lac:30 per cent epoxy were found to be better in performance than blends of 50 per cent lac:50 per cent epoxy and blends of 30 per cent lac:70 per cent epoxy resins, baked at 200°C for different time intervals. Adhesion and acid resistance of lac‐epoxy blends were very good compared with the parent resins.Research limitations/implicationsThe spectral studies on lac‐epoxy blends were done qualitatively. Although desirable, quantitative studies could not be carried out, due to the inherent difficulties in handling the resins.Practical implicationsLac‐epoxy blends may find an important role in printing inks, varnishes and finishing industries owing to their very good adhesion, gloss, scratch hardness and resistance to the action of acids.Originality/valueAs of now, there is no record of specular‐reflectance and derivative spectrometric studies on lac‐synthetic resin blends. This paper represents the first attempt to obtain and correlate reflectance data with physico‐chemical changes. It also highlights the convenience of the method and the scope of sophisticated data analysis, including derivative spectrometry and spectral subtraction techniques.
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