Abstract

The theory of spontaneous emission presented by Weisskopf and Wigner [V. Weisskopf and E. Wigner, Z. Phys. 63, 54 (1930)] provides an excellent approximation of the actual decay that atoms undergo on optically allowed transitions. However, the theory cannot be rigorously correct since it leads to a Lorentzian spectrum that extends to negative frequencies. Within the rotating-wave approximation, we derive a closed-form expression for the spectrum that is valid for all frequencies.

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