Abstract
The A′2u 3Π state of I2 is observed in a free-jet expansion of I2 in Ar, where it is prepared by ArF laser irradiation. Laser excitation spectra are recorded for 37 bands in the υ′←0″ progression of the D′2g(3P2)←A′ transition. The spectra display rotational temperatures of ∼5 K. At the 0.08 cm−1 resolution of the probe laser, rotational congestion near the band origins necessitates analysis by a nonlinear least-squares contour simulation method. Subsequent correlated fits of the band-by-band results are combined with other results to produce global constants valid for υ′=0–86, υ″=0–32.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
