Abstract
Electroionization spectra of HBr and DBr are measured and analyzed between the ionization threshold and 25 eV. Several negative-ion states having configurations (4pσ) (4pπ)4 5s2, 5p2, and 4d2, associated with Rydberg states converging to the 2Σ+ limit, have been identified. Other structures result from the excitation of the inner 4sσ electron. Finally, data on DBr are used to confirm the interpretation.
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