Abstract

IR spectra of yellow arsenic have been studied in the 700–30 cm −1 range within the 87–300 K temperature interval. A reversible phase transition has been observed at 223 K. Yellow arsenic is shown to exist in the form of molecular crystals. A comparison of the spectra of the higher- temperature phase of As 4 with those of the α-phosphorus leads to the suggestion that given phase of arsenic forms plastic crystals with a cubic lattice.

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