Spectroscopic study of double sodium-yttrium fluoride crystals doped with erbium Na0.4Y0.6F2.2:Er3+: I. Intensities of luminescence spectra and kinetics of luminescence

Abstract

Na0.4Y0.6F2.2:Er3+ (NYF:Er) crystals with an erbium concentration as high as 100 at. % (Na0.4Er0.6F2.2) were grown by the Bridgman-Stockbarger method. The optical spectra were investigated at low (6 K) and room temperatures. It is shown that the absorption spectrum of NYF:Er crystals contains wide bands (790–801 and 965–980 nm) corresponding to the emission range of laser diodes. The peak absorption cross section σa for the band peaked at λ=970.4 nm is 0.15×10−20 cm2. On the basis of the analysis of the absorption and luminescence spectra at low (6 and 12 K) temperatures, the structure of the Stark splitting of erbium levels was determined as a structure of quasi-centers for which Stark components are inhomogeneously broadened. The oscillator strengths of the transitions from the ground state of erbium to excited multiplets were calculated from the absorption spectra measured at T=300 K, and the intensity parameters Ωt were determined by the Judd-Ofelt method: Ω2=1.65×10−20 cm2, Ω4=0.56× 10−20 cm2, and Ω6=1.01×10−20 cm2. These values of the intensity parameters were used to calculate the probabilities of radiative transitions and the branching ratios. The rates of multiphonon nonradiative transitions in NYF: Er were estimated. The luminescence decay kinetics for radiative levels of erbium ions upon their selective excitation by nanosecond laser pulses was studied. The intracenter lifetimes of radiative levels of erbium ions were determined from the luminescence kinetics upon selective ion excitation by low-intensity light in a sample with a low erbium concentration (0.5%). It is demonstrated that, with an increase in temperature from 6 to 300 K, luminescence from the 4 G 11/2, 2 G(H)9/2, and 4 F 9/2 levels is quenched as a result of multiphonon nonradiative transitions. Luminescence from the 4 I 9/2 level is quenched only insignificantly with increasing temperature, and no quenching of luminescence from the 4 I 11/2 and 4 I 13/2 levels is observed. The spectra of steady-state luminescence of NYF:Er(0.5–15%) crystals were investigated upon broadband excitation by UV and UV-visible lamp light and selective time-resolved laser excitation. It is shown that low-lying levels of erbium ions separated by an energy gap smaller than 2500 cm−1 are populated via cascade mechanisms. On the basis of the results obtained, it is concluded that NYF:Er 3+ crystals are promising candidates for active media of tunable diode-pumped lasers.