Abstract
Both the electron micrographs and the UV-vis-near-IR reflectance spectra show that samples of MgO-CoO diluted solid solutions can be prepared in the form of cubelets where 98-96% of the surface ions are located on the (100) faces. CO adsorption at 77 K on the (100) faces occurs on both Mg/sup 2 +/ and Co/sup 2 +/ ions with formation of sigma-bonded Mg/sup 2 +/-CO and (sigma-..pi..)-bonded CO/sup 2 +/-CO carbonyls. CO parallel oscillators adsorbed onto Mg/sup 2 +/ ions extensively interact via dipole-dipole coupling as found on metals. CO molecules adsorbed onto isolated Co/sup 2 +/ ions are decoupled. An interaction occurs between Co/sup 2 +/-CO species and the adjacent Mg/sup 2 +/-CO ones via an inductive effect transmitted through the solid.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
