Spectroscopic studies on Co(II), Ni(II) and Cu(II) complexes with a new macrocyclic ligand: 2,9-dipropyl-3,10-dimethyl-1,4,8,11-tetraaza-5,7:12,14-dibenzocyclotetradeca-1,3,8,10-tetraene

Abstract

Cobalt(II), nickel(II) and copper(II) complexes containing a tetradentate macrocyclic nitrogen donor ligand i.e. 2,9-dipropyl-3,10-dimethyl-1,4,8,11-tetraaza-5,7:12,14-dibenzocyclotetradeca-1,3,8,10-tetraene have been synthesized and characterized by elemental analysis, molar conductance, magnetic moments, mass, 1H NMR, IR, electronic and EPR spectral studies. All the complexes are of high spin type and posses four-coordinated tetrahedral, five-coordinated square pyramidal and six-coordinated octahedral/tetragonal geometry. The ligand and its metal complexes were also screened against the growth of some bacteria and plant pathogenic fungi in vitro.