Abstract
Optical spectroscopy and Judd–Ofelt analysis were performed on a BaY2F8:Sm3+ crystal and used to guide the potential application of BaY2F8:Sm3+ as a laser material. Crystals were characterized by polarized absorption spectroscopy, fluorescence emission, and fluorescence lifetime measurements. The H69/2 and H67/2 manifolds are of most interest for visible lasers. This investigation seeks to capture the behavior of the samarium ion in a barium–yttrium–fluoride host from the UV–vis into the near-infrared wavelength regions.
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