Abstract
Chiral J-aggregates of meso-tetrakis(4-sulfonatophenyl)porphyrin (TPPS[Formula: see text] have been obtained in ethanol solution triggered by addition of both enantiomeric forms of tartaric acid. A detailed spectroscopic investigation has been performed on aggregates obtained by a well-defined mixture protocol of reactants. Our findings show as both aggregation process and induced supramolecular chirality essentially depend on the concentration of the reactants. Contrary to what occurs in aqueous solution, TPPS4 in ethanol solution shows: (i) at low porphyrin concentration, an aggregation behavior characterized by a L-tartaric acid threshold whereas the D-tartaric does not work even at high concentrations, so revealing an enantiomeric discrimination; (ii) at high porphyrin concentration, a large kinetic discrimination of D- vs. L-enantiomer.
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