Abstract
The adsorption and decomposition of methylamine on a Pt(111) surface have been investigated, using infrared reflection-absorption spectroscopy (IRAS) and high resolution electron energy loss spectroscopy (EELS). At 85 K, methylamine is found to adsorb molecularly on Pt(111). After heating the methylamine covered surface to temperatures in the range from 350 to 390 K, new infrared bands at 3371, 1565 and 1325 cm −1 are observed, indicating the presence of a new surface species which is formed by the dehydrogenation of adsorbed CH 3NH 2. These bands which shift to 2544, 1440 and 1296 cm −1 when using CH 3ND 2, are assigned to the NH (ND) stretching, CN stretching and CH bending modes of an adsorbed HCNH (HCND) species, respectively. The CH stretching band which is not detectable by IRAS is clearly observed at 2965 cm −1 using off-specular EELS.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
