Spectroscopic characterization of N,N'-bis(salicylidene)pentane-1,3-diamine nickel(II) complex

Abstract

The <TEX>$N_2O_2$</TEX> tetradentate Schiff base ligand, N,N'-bis(salicylidene)pentane-1,3-diamine (Salpn), coupled with 1:2 concentration ratio of 1,3-diaminopentane and salicylaldehyde was used to produce a series of macrocyclic Nikel(II) complexes. In the metal complexation, it was observed that Salpn macrocyclic ligand can adopt more than a metal ion giving an unique multinuclear metal complexes including Ni(II)Salpn and <TEX>$Ni(II)_3(Salpn)_2$</TEX>. Characteristic IR <TEX>${\upsilon}(M-O)$</TEX> peaks for Ni(II)Salpn and <TEX>$Ni(II)_3(Salpn)_2$</TEX> were observed to be <TEX>$1028cm^{-1}$</TEX> and <TEX>$1024cm^{-1}$</TEX>, respectively. Characteristic UV-Vis absorption <TEX>${\lambda}_{max}$</TEX> peaks for <TEX>$Ni(II)_3(Salpn)_2$</TEX> were observed to be 241nm and 401 nm. Structural characterization of <TEX>$Ni(II)_3(Salpn)_2$</TEX> by NMR exhibits that the salicylidene ring moiety has two different resonance signals originated from the magnetically asymmetric diligand and trinuclear bis complex. Complete NMR signal assignments and characterizations elucidating structural features of <TEX>$Ni(II)_3(Salpn)_2$</TEX> were described in detail.