Abstract
The solid state reactions of hemin with potassium acetate, KSCN, and Ag2SO4 were monitored using IR, Mössbauer and XRD techniques. These salts do not react at the peripheral propionic acid groups of hemin but form high spin complexes with hemin at the iron site. These complexes can be considered as ionic where the anions are coordinated to the metal through electrostatic interactions.
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