Spectroscopic characterization and reactivity studies of a copper(II) iminoxyl radical complex.

Abstract

A CuII complex (1) of a bis-pyridine-dioxime ligand and its one-electron oxidized analog (1-ox) were thoroughly characterized by various spectroscopic techniques, including X-ray absorption spectroscopy. 1-ox was found to be a CuII complex of a ligand iminoxyl radical and represents the first example of such a type. Reorganization energy (λ) of 2.12 eV was determined for the 1-ox/1 couple, which is considerably higher than the type 1 protein and synthetic CuIII/II(OH) complexes.