Abstract
The stoichiometric ratio and stability constants of iron(III) complexes with 1,n-di-O-salicyloylalkane-1,n-diols (n = 2 - 8) and N,N'-disalicyloyl-1,n-alkanediamines (n= 2 - 4) were determined spectrophotometrically. In 61.10% aqueous ethanol, the iron-to-ligand ratio is 1 : 1 (FeL+). The stability constants of the complexes were measured at 298 K and μ = 0.5 mol dm-3 (LiCl). Since the determination was performed in a glycinate buffer, the constants were corrected for the side reaction of iron(III) with glycine.
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