Abstract
A sensitive Spectrophotometric method for the determination of iron with tiron and a cationic surfactant, cetylpyridinium chloride, at pH 5.6 is reported. The complex is extracted into a chloroform-propan-2-ol (4∶1) mixture and shows maximum absorbance at 520 nm. Beer's law is obeyed in the range 1–14 μg/ml with an average molar absorptivity of 15800 l mol−1 cm−1. The molar ratio as determined by Job's method for Fe:tiron:CPC is 1∶4∶3. Interferences by various ions are examined. Zr, Ti and Mo interfere heavily. The method is applied for the determination of iron in Al-based and Cu-based alloys, using appropriate masking agents.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
