Abstract
The stability constant of gallium(III) monothiocyanate in DMSO at 25 °C has been determined spectrophotometrically using equimolar mixtures of gallium(III) and iron(III) perchlorates as constant-ionic-strength media. Formation of the complex has been studied calorimetrically. The derived thermodynamic parameters are: ΔG°=–20.0 ± 0.7 kJ mol–1, ΔH°= 11.1 ± 0.2 kJ mol–1 and ΔS°= 104 ± 3 J K–1 mol–1.
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Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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