Abstract
As a continuation of our previous studies on copper(II) complexes with a bidentate Schiff base derived from 5-bromosalicylaldehyde and α-aminopyridine, we have investigated the electronic spectra of the cobalt(II) complex with this ligand. The complex is a red crystalline compound soluble in common solvents, such as chloroform, dioxane, dimethyl formamide, dimethyl sulfoxide, and methanol. The time-elapsed spectral measurements of the complex and ligand, as well as conductivities of the complex in chloroform and dioxane solutions, are presented and discussed. Molar conductivities indicate that the complex exists as a nonelectrolyte in nonpolar solvents and as a 1:1 or 1:2 electrolyte in polar solvents. The ligand-field parameters (CFM/AOM) for the complex in chloroform solution are estimated and discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.