Spectral study of the complexation of Nd(III) with glutathione reduced (GSH) in the presence and absence of Zn(II) in aquated organic solvents

Abstract

Studies on the difference in energy parameters and comparative absorption spectrophotometry involving 4f-4f transitions on Nd(III) and glutathione reduced (GSH) in the absence and presence of Zn(II) have been carried out in aquated organic solvents (50 : 50) like methanol, dioxane, acetonitrile and dimethylformamide. Variations in the spectral energy parameters — Slater-Condon (F k ) factor, Lande spin-orbit coupling constant (ξ4f), nephelauxetic ratio (β), bonding parameter (b 1/2) and percent covalency (δ) — are calculated and correlated with binding of Nd(III) with GSH in presence and absence of Zn(II).