Abstract

A discharge of nitrogen gas, as created in a microwave-induced plasma, exhibits a very dense molecular emission line spectrum. Emission spectra of this kind could serve as wavelength calibrators for high-resolution astrophysical spectrographs in the near-infrared, where only very few calibration sources are currently available. The compilation of a spectral line list and the characterization of line intensities and line density belong to the initial steps when investigating the feasibility of potential wavelength calibration sources. Although the molecular nitrogen spectrum was extensively studied in the past, to our knowledge, no line list exists that covers a continuous range of several thousand wavenumbers in the near-infrared. We recorded three high-resolution ($\Delta \tilde{\nu} = 0.018$cm$^{-1}$) spectra of a nitrogen gas discharge operated at different microwave powers. The nitrogen gas is kept inside a sealed glass cell at a pressure of 2mbar. The emission lines in the spectra were fitted by a superposition of Gaussian profiles to determine their position, relative intensity, and width. The line parameters were corrected for an absolute wavelength scale, instrumental line broadening, and intensity modulation. Molecular and atomic transitions of nitrogen were identified with available line positions from the literature. We report line lists with more than 40000 emission lines in the spectral range $4500-11000$cm$^{-1}$ ($0.9-2.2$$\mu$m). The spectra exhibit emission lines over the complete spectral range under investigation with about $350-1300$ lines per 100cm$^{-1}$. Depending on the microwave power, a fraction of $35\% - 55\%$ of all lines are blended. The total dynamic range of the detected lines covers about four orders of magnitude.

Highlights

  • High-resolution near-infrared spectroscopy is an increasingly important tool in astrophysics

  • We present the characterization of a nitrogen gas discharge observed in the near-infrared with a Fourier transform spectrometer (FTS)

  • Using FTS observations of a frequency-locked diode laser with a line width of ≈100 kHz, we found that the true instrumental line spread (ILS) tends to be slightly broader than the theoretical value, but the difference is less than 10%

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Summary

Introduction

High-resolution near-infrared spectroscopy is an increasingly important tool in astrophysics. Molecular emission spectra, e.g., from N2 or CN, can be a viable alternative for wavelength calibration (Boesch et al 2014): a discharge of nitrogen gas exhibits a very dense line spectrum in the near-infrared, in contrast to hollow cathode lamps; the frequency of all lines are defined by physical laws not supposed to change over time, in contrast to FabryPerot etalons; and the equipment is relatively cheap, in contrast to laser frequency combs. The spectrum of molecular nitrogen has been extensively studied in the past, a line list based on high-resolution observations over a wide range in the near-infrared, to our knowledge, does not exist. We present the characterization of a nitrogen gas discharge observed in the near-infrared with a Fourier transform spectrometer (FTS). For the discharge operated at different MW powers, we investigate the change in line width of detected lines and in line intensity of identified atomic nitrogen

Experiment
Data analysis
Noise level
Peak finding and peak fitting
Correction of absolute wavenumber scale
Correction for instrumental resolution
Correction of line intensities
Identification of molecular nitrogen lines
Atomic line identification
Examples of line fitting
Results
Spectral line list
Line intensities
Line density
The influence of different MW powers on line width and intensity
Conclusion
Full Text
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