Abstract

Rotational structure of [2Π3/2]6s:2g Rydberg state of bromine has been studied by high resolution resonance enhanced (2+1) multiphoton ionization spectroscopy and computational simulation. Excellent agreement between theoretical analysis and experimental results was achieved. Spectral difference for two-photon transitions to Rydberg states of [2Π3/2]6s:2g and [2Π3/2]4d:1g with different angular momenta Ω is discussed.

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