Abstract
The rotational spectrum of cyanocyclobutane has been investigated in the region 18.0–40.0 GHz. Only A-type transitions were observed. R-branch assignments have been made for the ground state and the first three excited states of the ring puckering mode as well as the first two excited states of the out-of-plane cyano-bending mode. The microwave data are consistent with a bent equilibrium ground state for the ring with the cyano-group in the equatorial position. The dipole moment components were determined to be μ a = 4.04 ± 0.09 D and μ c = 0.92 ± 0.03 D with the total dipole moment, μ, having a value of 4.14 ± 0.09 D.
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