Abstract
The interionic structure in methylene chloride of trans-[Ru(PMe3)2(CO)(COMe)(CH2-pz2)]BPh3R (where pz = pyrazolyl ring; R = Me, n-Bu, n-Hex, and Ph) complexes has been investigated by the detection of interionic contacts in 1H NOESY NMR spectra. We observed an unexpected specificity of interionic contacts that allowed, for the first time, the estimation of reasonable average interionic distances by measuring the kinetic of 1H NOE buildup.
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