Abstract
Abstract Environment dependence of the selectivity in oxidation of a pair of associating thiols was examined in binary solvent mixtures of an alcohol or acetonitrile with water and an organic cosolvent. The discrimination between the two nonpolar groups (n- and i-C5H11 groups, phenyl and p-tolyl groups, or n- and i-C4H9 groups) of one of the thiols was found to occur more specifically in aqueous media than in the corresponding nonaqueous media.
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