Abstract
AbstractFree electrophoresis, differential spectral UV analysis, and the determination of the coefficients of selective sorption were used to investigate, in aqueous solutions of halides, the behavior of two polycations, poly[1(2‐hydroxyethyl)pyridinium methacrylate] and poly[1(2‐hydroxyethyl)trimethylammonium methacrylate]: i.e., one species with and the other without a pyridine ring in the side chain. Electrophoretic data were used to estimate the length of the electrophoretic segment and the approximate charge of the polyion in solutions of the individual salts. A comparison of the data showed that the interaction is not due to the presence of the pyridine ring in the side chain and that the order of activity of the halide anions is the same for both types of polymers.
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