Abstract
Specific heat of (CH 3 NH 3 ) 5 Bi 2 Cl 11 was measured by adiabatic calorimetry between 13 K and 325 K. A typical second-order type of anomaly was observed at 307.4 K. The enthalpy and entropy of transition were determined as 3.06 kJ mol -1 and 10.6 J K -1 mol -1 , respectively. A broad hump in the curve of specific heat was found around 160 K. Its contribution was estimated as the excess specific heat extending from about 100 K to 200 K over an assumed normal base line, which results in the values of enthalpy and entropy as 1.57 kJ mol -1 and 9.85 J K -1 mol -1 , respectively. The phase transition in the crystal was discussed in connection with such specific heat anomalies.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
