Specific features of the luminescence of silicate glasses with silver introduced by ion exchange

Abstract

The luminescence spectra of silicate glasses with silver introduced by ion exchange have been investigated. It is shown that silver introduced into glass by ion exchange exists not only in the form of ions, but also as neutral atoms and charged and neutral molecular clusters, which provide intense luminescence in the visible spectral range. Cerium ions in glass facilitate the formation of neutral molecular silver clusters, due to which the luminescence intensity increases. It is shown that Agn-Cex+ complexes can be formed in glass containing cerium ions and neutral molecular silver clusters.