Specific features of nonstoichiometric interpolymer complexes of poly(acrylic acid) and poly(ethylene glycol) as protectors of copper nanoparticles in aqueous sols

Abstract

Advantages of interpolymer complexes for use as amphiphilic protectors of nanoparticles during the formation and stabilization of sols are considered. The effects of the ratio of poly(acrylic acid) and poly(ethylene glycol) and the molecular mass of poly(ethylene glycol) on the mean size and size distribution of copper nanoparticles in sols formed via the reduction of divalent copper ions in mixed aqueous solutions of these polymers are investigated. It is shown that sols of metal nanoparticles with small sizes and narrow size distributions are formed even when poly(ethylene glycols) with chain lengths below the “critical” chain length and a small PEG-to-PAA base-molar ratio are used. This is evidence for efficient protection of the formed copper nanoparticles by the interpolymer complex PEG-PAA under conditions of its instability and for self-organization of oligomeric PEG chains in complex macromolecular shields of nanoparticles.