Abstract

The perovskite Bi0.5Ca0.5FeO3 has been investigated using the Mossbauer effect at temperatures of 295 and 675 K. The measured temperature of the magnetic phase transition (Neel temperature) is TN = 640 ± 10 K. Above the Neel temperature, there are two nonequivalent structural states of iron ions. In the perovskite Bi0.5Ca0.5FeO3 at room temperature, there are seven most probable nonequivalent magnetic states of iron ions with significantly different values of the hyperfine interaction parameters. Four iron states correspond to Fe3+ ions in the octahedral oxygen environment, and three iron states correspond to Fe3+ ions in the tetrahedral oxygen environment.

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