Abstract
Speciation of [ZrClx(OH).y(H2O)z]q by electrochemical measurements. Speciation of zirconium complexes is important for liquid-liquid extraction of the metal. Spectrophotometry cannot be used as speciation method because d0-complexes form in an aqueous solution, and therefore the use of a chloride selective electrode is tested by firstly applying it to iron(III) chloride speciation, which is known.
Highlights
Authors: Roné Kemp1 Gerhard Lachmann1 Derik J. van der Westhuizen1 Cornelius J. le Roux1 Henning M
Speciation of zirconium complexes is important for liquid-liquid extraction of the metal
Spectrophotometry cannot be used as speciation method because d0-complexes form in an aqueous solution, and the use of a chloride selective electrode is tested by firstly applying it to iron(III) chloride speciation, which is known
Summary
Authors: Roné Kemp1 Gerhard Lachmann1 Derik J. van der Westhuizen1 Cornelius J. le Roux1 Henning M. Affiliations: 1School of Physical and Chemical Science, North-West University, Potchefstroom Campus, South Africa & Krieg, H.M., 2014, ‘Spesiëring van [ZrClx(OH).y(H2O)z]q deur elektrochemiese metings’, Suid-Afrikaanse Tydskrif vir Natuurwetenskap en Tegnologie 33(1), Art. Note: A selection of conference proceedings: Student Symposium in Science, 27 and 28 October 2012, North- West University, South Africa.
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