Abstract

Atoms and molecules in highly excited electronic states ('Rydberg atoms') have been the object of broad scientific research for almost a century. Despite this long history, the field of research has never lost its buoyancy, and recent years in particular have seen a tremendous revival of interest in the physics of Rydberg atoms and molecules from many different perspectives. Rydberg systems touch a wide range of research areas including, among others, ultralong-range molecules, artificial ('designer') atoms, quantum chaos, quantum information, ultracold Rydberg gases and plasmas, and anti-hydrogen formation. Due to the many fields involved, the physical insight and technical know-how are scattered over different communities. The goal of this special issue is to provide an integral overview of the latest developments in this highly innovative research field and to make the physical knowledge available to a wide audience. Groups from various fields of atomic, molecular and optical physics as well as condensed matter and plasma physics have contributed to this issue, which therefore spans a wide range of areas connected through the common theme: 'Rydberg physics'.This name was given to a four-week International Workshop and Seminar which was held from 19 April to 14 May 2004 at the Max-Planck-Institut für Physik Komplexer Systeme in Dresden, Germany, and organized by the three of us. The workshop and seminar programme was a very successful mixture of topics bringing together colleagues working in different but related areas of research centred about the physics of highly excited Rydberg atoms and molecules. We would like to take this opportunity to express our gratitude to the organization team of the MPI-PKS Dresden, especially the Director, Jan-Michael Rost, and the Visitors' Programme coordinator, Mandy Lochar. The generous support of the Max Planck Society, which made this successful workshop and seminar possible, is also gratefully acknowledged. Inspired by the great response to the 'Rydberg physics' conference we thought that it would be timely and appropriate to recognize the importance of Rydberg physics with a special issue of a scientific journal. The 'unbureaucratic' and highly efficient editorial and publishing team of Journal of Physics B: Atomic, Molecular and Optical Physics (J. Phys. B) allowed this to become a reality; it was a real pleasure for us to serve as guest editors. Unlike a conventional conference proceedings, this special issue has not been restricted to participants of the 'Rydberg physics' conference, and all the original papers contained in it have been peer-reviewed to the usual high standards of J. Phys. B.The variety and integrated discussion on the physics of Rydberg systems during the 'Rydberg physics' conference is reflected in the papers presented here. We have tried to group the papers according to the subject areas which are addressed. The first part of this special issue is devoted to high-resolution spectroscopy revealing deeper insights into the structure of Rydberg atoms and molecules as well as electronic interaction processes. The second part contains experimental and theoretical investigations on the influence of external static and oscillatory fields on Rydberg atoms. The third part takes account of the newly established field of ultracold Rydberg gases and plasmas with special emphasis on the appearance of ultralong-range interactions in these systems. Finally, the issue is concluded by articles on new developments including 'exotic' Rydberg systems.We would like to thank all of the participants of the 'Rydberg physics' workshop and seminar, and, in particular, thecontributors to this special collection of papers, for their involvement. We are deeply indebted to the J. Phys. B editorial and publishing team both for making its realization possible in an extremely efficient way, and for the journal's commitment to the physics of Rydberg systems. We are impressed by the continuing progress in this fascinating and rapidly growing field of research and we look forward to many more thrilling and surprising achievements.

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