Abstract

It was shown that the influence of guest molecules on the structure of porous coordination polymers (PCP) can be considered as the manifestation of a template effect. The presence of such molecules and their nature affect the composition of the PCP and the topology of the polymer framework and can also determine the chirality of the crystal lattice. The criteria that can be used to reach conclusions about the special features of the template effect during the formation of PCPs are analyzed.

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