Spatio-temporal progression and influencing mechanism of local wetting in membrane distillation

Abstract

Membrane wetting is the bottleneck of membrane distillation (MD) in real applications. However, rare information is attainable on the spatial inhomogeneity and temporal instability of local wetting behavior along the membrane. In current study, the influences of operating conditions (i.e., feed temperature, velocity, and concentration) and membrane hydrophobicity on the spatio-temporal progression of local wetting along the membrane were evaluated using a non-invasive and online monitoring technique – ultrasonic time-domain reflectometry (UTDR). UTDR measurements could successfully distinguish local wetting dynamics and were validated by the off-line characterization of the wetting layer thickness via a scanning electron microscopy with energy-dispersive x-ray spectroscopy. Observations showed that the local wetting depth decreases along the feed flow direction. This wetting heterogeneity would be impaired with increasing surfactant concentration, feed temperature, and crossflow velocity. However, enhancing membrane hydrophobicity obviously reduced the rate of local wetting but hardly affected its nonuniform distribution. The wetting heterogeneous propagation at different locations is dominated by the nonuniform mass and heat transfer characteristics along the membrane based on the computational fluid dynamics (CFD) simulation. Localized wetting prevention near the module inlet is therefore critical to ensure stable MD operation.