Spatiotemporal ecological risk evaluation and source identification of heavy metals and nutrients in the water and lake surface sediment in a protected catchment area of a volcanic lake.

Abstract

Indonesia has numerous lakes; however, research on the spatiotemporal sediment quality and source identification in lakes remains limited. The overaccumulation of heavy metals and nutrients in lakes severely threatens aquatic ecosystems. This study aims to identify potential sources of metallic deposits (Cu, Pb, Cr, Fe, Al, and Cd) and nutrients (TN and TP) in lake-surface sediment, utilizing enrichment factors (EF), geoaccumulation indices (Igeo), potential ecological risk indices (Er), and risk indices (RI). Multivariate statistical analyses, including principal component analysis (PCA) and Pearson's correlation analysis, were conducted to pinpoint pollution sources linked to land use. Eight sampling sites for surface sediment and water were examined in both wet and dry seasons at Menjer Lake, chosen for its diverse applications in tourism, hydropower, floating net cages, and extensive agriculture in its catchment. Correlation and PCA results indicated that Pb, Fe, and Al mainly originate from tourism, while Al, Fe, TN, and TP are associated with agriculture. The highest average loading from land use was observed in agriculture (> 0.8), floating net cages (> 0.76), and tourism (> 0.68). Furthermore, the highest loading from nutrients and all metals were TP (> 0.71) and all metals (> 0.35), respectively. Ecological risk assessment revealed low to moderately polluted EFs and Igeo in the dry season. However, Menjer Lake's Er and RI for heavy metals were generally classified as unpolluted.