Spatio-temporal variations of sedimentary metals in a large suburban lake in southwest China and the implications for anthropogenic processes

Abstract

Environment quality of suburban and urban lakes receives special attention due to their great impacted by human perturbations and important roles in ecosystem services. Herein, the spatio-temporal variations of 10 metal and metalloid elements in 13 sediment cores from a large suburban lake (Dianchi) were studied to explore the changes in sedimentary environment and pollution and their associations with human activities since the last century. Concentrations of each element were largely varied at spatial scales, but showed similar vertical trends among the profiles, suggesting comparable changes in sedimentary processes in each lake region. Cluster analysis showed two groups of elements: group I includes Al, Ti, Cu, Cr and Ni, and group II includes As, Cd, Hg, Pb and Zn. Temporally, concentrations of all elements were generally constant until the 1950s. Thereafter, group I elements along with the clay percentage started to decrease, indicating accelerated input of coarser soils due to strengthening human perturbation and changing land use. However, group II elements showed increasing values of concentrations, particularly the enrichment factors (EF = 1.0–10.8), which peaked between mid-1990s and 2000, indicating continued pollutants input with watershed economic development. With the implementation of environment management measures, pollution was initially restrained or reduced in recent decades as indicated by the stable EFs and sedimentary fluxes of Cd, Hg, Pb and Zn and decreasing values of As. Spatially, the stocks of anthropogenic As, Cd, Hg, Pb and Zn were higher in the northern while lower in the southern lake area. This spatial difference was mainly due to the large input of industrial and domestic wastewaters in the northern compared to the area in the southern that receives runoff from agricultural and forested land. Overall, the spatio-temporal patterns in accumulation of metal and metalloid elements in the lake reliably reflected the impacts of watershed human activities.