Spatial-temporal occurrence and sources of organochlorine pesticides in the sediments of the largest deep lake (Lake Fuxian) in China.

Abstract

Compared with shallow lakes, less attention has been paid on pollutions in deep lakes. Lake Fuxian is the largest deep lake and an important water resource in China. The knowledge on organochlorine pesticides (OCPs) in sediments of Lake Fuxian was rare. Fifteen surface sediments and one sediment core were collected from Lake Fuxian. Sediment chronology was dated with the activities of 137Cs and 210Pb. Twenty-one OCPs in the surface sediments and sediment core were analyzed by a GC-MS. Spatial and temporal occurrences of OCPs in the sediments of this lake were studied. Correlations, isomer ratios, and principal component analysis (PCA) were applied to apportion the sources of OCPs in the sediments of this lake. The OCPs in the sediments of Lake Fuxian were dominated by p,p'-DDT (4,4'-dichlorodiphenyltrichloroethane) and HCHs (hexachlorocyclohexane). The concentration of ΣOCPs in the surface sediments ranged from 0.42 to 67.5ngg-1, with an average of 42.3 ± 23.5ngg-1 (mean ± SD, n = 15). The concentration of ΣOCPs in the sediment core varied from 3.5 to 707.9ngg-1 in the period from 1950 to 2010, with an average of 167.7 ± 203.7ngg-1 (n = 24). The highest concentrations and fluxes of α-HCH, γ-HCH, and p,p'-DDT were found in the years of 1964 and 1967, respectively. The fluxes of HCH isomers in the sediment core decreased in the orders as γ-HCH > β-HCH > α-HCH in the period from 1950 to 2010. The concentrations of HCHs and p,p'-DDT in the sediments of Lake Fuxian were higher than those of most shallow and deep lakes in the world. HCHs and p,p'-DDT were derived from both the technical HCH and DDT and the usage of lindane and dicofol. Technical DDT and technical HCH may be used simultaneously, but technical DDT and lindane were not applied simultaneously in the catchment. Lindane was used not only in the period from 2002 to 2010 but also in the period from 1950 to 1964 in the catchment.