Abstract

Continuous monitoring of surface water is essential in terms of heavy metals investigation. Therefore, surface water quality is an environmental aspect which should be analyzed and monitored depending on its spatial distribution. The aim of this study is to provide an overview for evaluation of surface water pollution in the Mitrovica area by applying spatial distribution using Geographic Information System (GIS), geostatistical and non-geostatistical techniques. Nowadays, GIS with the geostatistics and non-geostatistics are very frequently used techniques in environmental monitoring studies. By providing the spatial distribution, there is possibility to place the pollution values in space. The surface water pollution caused by heavy metals (As, Cr, Cu, Ni, Pb, Zn and Cd) were sampled and analyzed from six monitoring stations in Sitnica river on different time series within three months countineously. The monitoring stations (samples) in Sitnica river were been distributed randomly. Pollution maps were produced using geostatistical and non-geostatistical (Spline and Kriging) approach. There were produced different pollution values in Sitnica river during the period of monitoring. Mainly the north part of Sitnica river has been poluted mostly with Heavy Metal Pollution Index (HPI) from 50 to 85 in the month of May, from 125 to 265 in the month of June and from 320 to 535 in the month of July. As well as the Metal Index (MI) from 0.60 to 2.05 in the month of May, June and July. The different statistical models were tested for geostatistical and non-geostatistical techniques in order to identify the best fitted technique for the pollution indices and the best interpolation techniques were selected on the basis of Mean Square Error (MSE), Mean Absolute Deviation (MAD), Root Mean Square Error (RMSE) and Mean Absolute Error (MAE) and Mean Absolute Percentage Error (MAPE). These statistical tested model have shown that the best fitted interpolation technique is Kriging because of the lowest values of MSE, MAD, RMSE, MAE and MAPE. In the study were involved statistical models such as correlation and regression, for showing the relation between time series datasets and interpolated pollution indices as well. The cartographic output derived from the study were raster maps (15m spatial resolution) which represent the spatial distribution of surface water pollution as a result of monitoring process on time series. It is our believe that the present study will be used as a reference study for further environmental investigation and monitoring in Mitrovica since.

Highlights

  • Water is a compound with specific chemical properties which can dissolve diverse compounds or keep them suspended (World Health Organization [WHO], 2007)

  • The study carried out the role of spatial interpolation techniques and Geographic Information System (GIS) in monitoring surface water, the case of Sitnica river

  • The study has demonstrated that GIS in conjuction with geostatistical techniques is a useful methodology for Sitnica river monitoring and assessment

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Summary

Introduction

Water is a compound with specific chemical properties which can dissolve diverse compounds or keep them suspended (World Health Organization [WHO], 2007). It allows to compile the maps of pollution distribution for whole study area, Sitnica river. In the present study these techniques will be used to interpolate the whole surface of the area based in the known points (samples/monitoring stations). HPI, MI, Geographic Information System and (non) geostatistical techniques are used to monitor and map the spatial distribution of surface water pollution. There detail objectives in this study are to; determine the level of concentration based in indices such as MI and HPI, in Sitnica river, develop an appropriate GIS system which will include spatial and non-spatial data of surface water monitoring, apply (non) geostatistical techniques in order to visualize surface water monitoring, analyse relationship between geostatistical and non-geostatistical techniques and relationship between time series monitoring, produce time series surface water monitoring maps. The present research provided realiable monitoring and assessment results for the surface water (Sitnica river) in Mitrovica, Kosovo

Study area
Monitoring indices
Data sources
Data processing
Spatial database and Thematic Layers
Serial thematic maps and spatial analysis
Diagram maps
Statistical analysis
Findings
Conclusions
Full Text
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