Abstract

Anthropogenically influenced transboundary catchment areas require an appropriately adapted exposure modelling. In such catchments, water management decisions strongly influence and override natural river hydrology. We adapted the existing exposure assessment model GREAT-ER to better represent artificially overprinted hydrological conditions in the simulations. Changes in flow directions and emission routes depending on boundary conditions can be taken into account by the adopted approach. The approach was applied in a case study for the drug metformin in the cross-border catchment of Vecht (Germany/Netherlands). In the Dutch part, pumps to maintain necessary water levels and minimum flow rates during dry periods lead to a reversal of the (natural) flow directions and as a consequence to additional pollutant input from the Lower Rhine/Ijssel along with a spatial redistribution of emissions in the catchment area. The model results for the pharmaceutical product metformin show plausible concentration patterns that are consistent with both monitoring results and literature findings at mean discharges and the effects of the changed hydrology in times of low natural discharges, namely an increase in polluted river sections under dry conditions due to the pumping activities. The adapted methodology allows for realistic application of the GREAT-ER model in anthropogenically modified catchments. The approach can be used in similar catchments worldwide for more realistic aquatic exposure assessment.

Highlights

  • River basin management in densely populated regions is a difficult and challenging task

  • Wiering et al (2010) state that integrative goals of river basin management are characterised by the connection and combination of different aspects of water systems, such as water quality and water quantity

  • Existing models for exposure assessment of chemicals in surface waters are usually not prepared to represent hydrological conditions that are strongly affected by anthropogenic interventions in a realistic way

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Summary

Introduction

River basin management in densely populated regions is a difficult and challenging task. Wiering et al (2010) state that integrative goals of river basin management are characterised by the connection and combination of different aspects of water systems, such as water quality and water quantity. Integrative river basin management puts forth the need for communication and cooperation between water management and other policy domains such as spatial planning, agriculture, housing or nature conservation. For large rivers in Europe, cross-border work has been common practice for years. Since the beginning of the new millennium, the Water Framework Directive (WFD, Directive 2000/60/EC 2000) and the European Flood Risk Directive (EFD, Directive on the assessment and management of flood risks; 2007/60/EC) are calling for this cross-border practice. The WFD strongly influences both national and regional water policy practices. In terms of the WFD, it is necessary to move towards transboundary, catchment-related risk assessment replacing old-fashioned national approaches within country borders (Coppens et al 2015; Vissers et al 2017)

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