Spatial distribution, sources and risk assessment of polycyclic aromatic hydrocarbons in the surficial sediments of the Egyptian Mediterranean coast

Abstract

The Egyptian Mediterranean coast (EMC) receives a considerable quantity of polycyclic aromatic hydrocarbons (PAHs). PAHs from EMC sediments were assessed to understand the effects of marine and riverine currents on their distribution. The concentrations of total PAHs ranged between 13,156–34,852 ng/g dw. PAH levels have increased even in areas far from the shoreline under the influence of riverine inputs from the Nile River; this is attributed to the tidally induced riverine freshwater re-suspension of surface sediments in the shallow near-shore section and re-precipitation in the fare stations. PAH levels generally increase as one moves from the western to the eastern part of the studied area, owing to the effect of the marine current. Diagnostic ratios pointed toward different pyrogenic sources. SQGs were used to assess the probability of observing adverse biological effects in benthic organisms in sediment samples. The toxic and mutagenic equivalent quotient for carcinogenic PAHs was extremely high.